Irgarol
Biocide used in antifoulings
Irgarol (Cybutryne) is a very effective herbicide which blocks the photosynthesis of plants. It is mainly used as active ingredient in antifouling coatings for hulls and underwater constructions.
Since the 1980s Irgarol has increasingly been used as substitute of the antifouling active ingredient Tributyl tin (TBT) which is banned in the European Union since 2003. Until 2011 it was also allowed to use Irgarol as an algicide for coatings of outer facades.
Since 2004 the German Umweltbundesamt (Federal Environment Agency) has been carried out extensive mesocosm studies in its test plant of artificial streams and ponds and has been analysed nationwide water samples for Irgarol. These results found entrance into the derivation of the environmental quality standards (EQS) for Irgarol in the context of the European Water Framework Directive (WFD) 2013/39/EC and into the risk assessment of the European biocide regulation 528/2012.
Irgarol is persistent in aquatic ecosystems, toxic to algae and underwater plants and toxic for reproduction to water snails.
Search data
Specimen
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Fine insoluble mineral or organic particles in the water phase
Sampling area
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Important, old-industrialised conurbation in Germany.
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Longest river in Germany
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Fourth largest river basin in Central Europe
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Region in the chemical triangle of Central Germany
Sampling period
2006 - 2012
Extended information
Links to external information and legislation
- Wie viel Antifouling vertragen unsere Gewässer? | Umweltbundesamt (external)
- Sicherung der Verlässlichkeit der Antifouling- Expositionsschätzung im Rahmen des EU-Biozid- Zulassungsverfahrens auf Basis der aktuellen Situation in deutschen Binnengewässern für die Verwendungsphase im Bereich Sportboothäfen | Umwelbundesamt (external)
- Fate-Studie Irgarol | Umweltbundesamt (external)
- Effect study "Irgarol" | Umweltbundesamt (external)
- Vom Ersatzstoff zum Problemfall? Der Antifouling-Wirkstoff Irgarol | Umweltbundesamt (external)
- Artificial stream and pond system | Umweltbundesamt (external)
- Directive 2013/39/EU of the European Parliament and of the Council of 12 August 2013 amending Directives 2000/60/EC and 2008/105/EC as regards priority substances in the field of water policy (external)
- Regulation (EU) No 528/2012 of the European Parliament and of the Council of 22 May 2012 concerning the making available on the market and use of biocidal products (external)
Literature
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Zeitreihenuntersuchung von Irgarol und den Azolfungiziden Tebuconazol und Propiconazol in Schwebstoffproben der Umweltprobenbank des Bundes (UPB)
Schulz, Volker
Jena: FOOD GmbH Jena Analytik-Consulting, 2013. - 32, Projektnummer (28 221), 2013